Sorribes, Ivan; Wienhoefer, Gerrit; Vicent, Cristian; Junge, Kathrin; Llusar, Rosa; Beller, Matthias published the artcile< Chemoselective Transfer Hydrogenation to Nitroarenes Mediated by Cubane-Type Mo3S4 Cluster Catalysts>, Electric Literature of 112-63-0, the main research area is molybdenum sulfur cluster catalyst transfer hydrogenation nitro arene heteroarene; aromatic amine preparation.
Cubane-type Mo3S4 cluster compounds catalyzed transfer hydrogenation to nitro arenes or nitro heteroarenes to give aromatic amines. E.g., in presence of formic acid and NEt3 as the reducing agent, [Mo3S4H3(dmpe)2]BPh4 catalyzed the transfer hydrogenation of 4-O2NC6H4NH2 to give 90% p-phenylenediamine.
Angewandte Chemie, International Edition published new progress about Aromatic amines Role: SPN (Synthetic Preparation), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics