Smith, Hilton A.; Fort, Tomlinson Jr. published the artcile< The kinetics of the base-catalyzed hydrolysis of the methyl esters of cyclohexanedicarboxylic acids>, Application of C19H34O2, the main research area is .
Saponifications involving the monomethyl esters and alkali are strictly 1st order with respect to alkali and 1st order with respect to ester. For the cis-1,2, trans-1,2, trans-1,3, and cis-1,4 forms of the dimethyl esters saponification of the 1st ester group was so much more rapid than for the 2nd that in the early stages of the reaction (up to some 20%) the kinetic behavior was 2nd order. For each ester there is a large decrease in the saponification rate of the 2nd ester group as compared with the 1st. On the basis of the ratios of the 1st- and 2nd-rate constants for saponification of the esters studied, the separation of the 2 ester groups shows the following order: trans-1,4 > cis-1,3 > cis-1,4 > trans-1,3 > trans-1,2 > cis-1,2. The relative entropies of activation for the saponification reactions based on the monomethyl ester of cis-1,2-cyclohexanedicarboxylic acid are given.
Journal of the American Chemical Society published new progress about Entropy. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application of C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics