Kanzaki, Chisako; Nakadozono, Takuya; Numata, Munenori published the artcile< Creation of Discrete 1D Microstructures: Directional Dissociation from the Ends of a Metastable Supramolecular Polymer>, Synthetic Route of 112-63-0, the main research area is metastable supramol polymer directional dissociation microstructure.
One major concern in supramol. chem. is how to place different intermol. interactions in a desired position, especially at the terminal ends, of 1D structures. A solution to the problem is co-assembly in microflow. We demonstrate that kinetic co-assembly of two kinds of amphiphilic oligo(p-phenylenevinylene) mols. with different amide groups result in metastable nanofibers where stronger hydrogen-bonding interactions are regularly inserted as stabilizing wedges. It is found that decomposition of the nanofibers from the ends is suppressed at the wedges, leading to the creation of discrete 1D structures with capped ends (length dispersity Lw/Ln≤1.2), which act as a micrometer-sized building blocks that can be used for further hierarchical assembly.
ChemPlusChem published new progress about Hydrogen bond. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Synthetic Route of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics