Tilford, R William’s team published research in Chemistry of Materials in 2006-10-31 | 112-63-0

Chemistry of Materials published new progress about Polyesters Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation) (polyborate network). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application of C19H34O2.

Tilford, R. William; Gemmill, William R.; zur Loye, Hans-Conrad; Lavigne, John J. published the artcile< Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network>, Application of C19H34O2, the main research area is polyboronate ester synthesis dehydration.

A covalent organic framework (COF-18Å) based on poly(boronate ester)s has been successfully synthesized through a facile dehydration process in 85-95% isolated yield. Spectroscopic characterization confirms formation of the intended ester linkages as the key structural motif forming infinite 2D hexagonally porous sheets. Powder x-ray diffraction studies were used to determine the stacking orientation between the ester-linked sheets, such that atoms in adjacent layers lie directly over each other, resulting in a hexagonal array of 1D, 18 Å pores. COF-18Å exhibits rigid, thermally stable (to 500 °C) pores with high surface area (1260 m2/g) and a micropore volume of 0.29 cm3/g.

Chemistry of Materials published new progress about Polyesters Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation) (polyborate network). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application of C19H34O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics