Crittall, MatthewR.; Rzepa, Henry S.; Carbery, David R. published the artcile< Design, Synthesis, and Evaluation of a Helicenoidal DMAP Lewis Base Catalyst>, Computed Properties of 112-63-0, the main research area is helical dimethylaminopyridine analog preparation Lewis base catalyst enantioselective esterification; alc benzylic secondary enantioselective esterification anhydride kinetic resolution.
The design, synthesis, and study of helical dialkylaminopyridine Lewis base catalysts (P)-I and (M)-I is reported. These catalysts displayed good to excellent levels of selectivity (S ≤ 116) in the kinetic resolution of chiral secondary alcs. R1CH(OH)R2 (R1 = Ph, R2 = Me, Et, t-Bu; R1 = 4-FC6H4, 2-MeC6H4, 2-naphthyl, 9-anthryl, etc., R2 = Me). Catalysts I displayed excellent reactivity with exceptionally low loadings of 0.05 mol.% effecting practical levels of selectivity in kinetic resolutions
Organic Letters published new progress about Aralkyl alcohols Role: PUR (Purification or Recovery), RCT (Reactant), SPN (Synthetic Preparation), PREP (Preparation), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.
Referemce:
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