Huang, Wei-Ming; Liao, Wei-Sheng; Lai, Yan-Ming; Chen, I-Wen Peter published the artcile< Tuning the surface charge density of exfoliated thin molybdenum disulfide sheets via non-covalent functionalization for promoting hydrogen evolution reaction>, HPLC of Formula: 112-63-0, the main research area is molybdenum sulfide sheet electrocatalyst exfoliation surface charge density tuning.
The scalable and facile generation of hydrogen fuel via water splitting requires robust and cost-effective earth-abundant electrocatalysts for hydrogen evolution reaction (HER). It is reported for the first time that the surface charge d. of exfoliated monolayer molybdenum disulfide (MoS2) sheets can be successfully tuned with the assistance of exfoliants, such as pyridinium tribromide (py), imidazole (i.m.), and chlorophyll (ch), and thereby significantly affect the kinetics of the HER. The surface charge potential of the exfoliated monolayer py-MoS2, i.m.-MoS2, and ch-MoS2 sheets are -33 mV, -22 mV, and -2 mV, resp. As the surface charge potential approaches zero, the Tafel slope required varies from 140 mV dec-1 for py-MoS2 to 45 mV dec-1 for ch-MoS2. Moreover, to achieve real-world applications, the exfoliated thin ch-MoS2 sheets were fabricated to form flexible composite papers, and they exhibited excellent electrocatalytic activity with further enhanced Tafel slope of 35 mV dec-1, which is nearly identical to that of bulk Pt, “”the gold standard”” for HER, an ultra-low onset potential of -42 mV and over 100 h of electrochem. durability. This convenient non-covalent functionalization method provides opportunities for many other applications of exfoliated thin MoS2 sheets and other two-dimensional transition metal dichalcogenides (2D-TMDCs).
Journal of Materials Chemistry C: Materials for Optical and Electronic Devices published new progress about Carbon nanotubes. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, HPLC of Formula: 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics