Nishikawa, Toshio; Urabe, Daisuke; Yoshida, Kazumasa; Iwabuchi, Tomoko; Asai, Masanori; Isobe, Minoru published the artcile< Stereocontrolled Synthesis of 8,11-Dideoxytetrodotoxin, Unnatural Analogue of Puffer Fish Toxin>, SDS of cas: 112-63-0, the main research area is asym synthesis deoxytetrodotoxin analog Puffer fish toxin synthon.
8,11-Dideoxytetrodotoxin, an unnatural tetrodotoxin analog, was synthesized in a highly stereoselective manner from a common intermediate in our synthetic studies on tetrodotoxin. The synthesis features neighboring group participation of trichloroacetamide for stereoselective hydroxylation, protection of ortho ester, and guanidine installation with Boc-protected isothiourea.
Organic Letters published new progress about Hydroxylation. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, SDS of cas: 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics