Month: February 2023

Volatile compounds and biogenic amines during the ripening of mold-ripened Civil cheese manufactured using three different strains of Penicillium roqueforti was written by Gurkan, H.;Yilmaztekin, M.;Cakmakci, S.;Hayaloglu, A. A.. And the article was included in Journal of Food Safety in 2018.Related Products of 659-70-1 This article mentions the following:

Three different strains of Penicillium roqueforti were used for the manufacture of mold-ripened Civil cheese and these cheeses were ripened at 4 and 10 °C for 90 days. Sixty-five volatile compounds were identified in the volatile fractions of the cheeses. The concentration of volatile compounds in cheeses was significantly affected ripening time temperature and by mold strains a lesser extent. 3-Methyl-1-butanol, 2-nonanol, Me dodecanoate, butanoic acid, and decanoic acid were the most frequently identified volatiles. Tryptamine, 2-phenylethylamine, putrescine, cadaverine, tyramine, spermidine, and spermine were also found. The most abundant biogenic amine was cadaverine. The formation of biogenic amines was significantly influenced by strain, ripening time, and temperature The biogenic amine content was found to be between 2.41 and 228.94 μg/g cheese. Ripening temperature and ripening time significantly influenced the formation of volatile compounds and biogenic amines. Practical applications : Moldy Civil is a traditional cheese variety produced in the eastern Anatolian region of Turkey and it is protected by geog. indication by Turkish Patent and Trademark Office (TURKPATENT) by 2010. It is manufactured using skimmed milk which is spontaneously acidified with native lactic acid bacteria and also the addition of preacidified whey. Three strains of P. roqueforti was used in Moldy Civil cheese-making and strains of the mold changed the volatile profiles and the levels of biogenic amines less than ripening time and temperature Me ketones and alcs. were the dominant groups in volatiles, while cadaverine was found to be principal biogenic amine in Moldy Civil cheese. Use of P. roqueforti strains contributed to the formation of the volatile fraction of the cheese; however, the level of biogenic amines changed by P. roqueforti strains a lesser extent. In the experiment, the researchers used many compounds, for example, Isopentyl 3-methylbutanoate (cas: 659-70-1Related Products of 659-70-1).

Isopentyl 3-methylbutanoate (cas: 659-70-1) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Related Products of 659-70-1

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Characteristics and risk assessment of organophosphate esters and phthalates in soils and vegetation from Dalian, northeast China was written by Wang, Yan;Zhang, Zihao;Bao, Meijun;Xu, Yue;Zhang, Lijie;Tan, Feng;Zhao, Hongxia. And the article was included in Environmental Pollution (Oxford, United Kingdom) in 2021.Computed Properties of C20H26O4 This article mentions the following:

We investigated the concentration, composition, and potential risk of organophosphate esters (OPEs) and phthalates (PAEs) in soils and vegetation from rural areas of Dalian, Northeast China. The residues of total OPEs and PAEs in soils were in the range of 33.1-136 ng/g dw (dry weight) and 465-5450 ng/g dw, while the values in plants were 140-2360 ng/g dw and 2440-21800 ng/g dw, resp. The concentrations of both chems. in the plant rhizosphere soils were significantly lower than those in the bulk soils, suggesting an enhanced degradation or uptake by plant. The contaminations in soils also varied for different land use types with the concentrations generally higher in paddy soils than those in maize soils. The OPE and PAE concentrations in plant leaves were slightly higher than those in their corresponding roots. The bioconcentration factors of OPEs & PAEs were significantly neg. correlated with their octanol-water partition coefficients A hazard assessment suggested potential medium to high risks from tricresyl phosphate (TMPP) and di-Bu phthalate (DNBP) for the agricultural soils in Dalian of China. Although the ecol. risks of OPEs and PAEs in the rhizosphere soils were lower than those in the bulk soils, the relevant risk could still endanger human health via oral intake of these plants. The daily dietary intakes of OPEs and PAEs via vegetable and rice consuming were estimated, and the result suggests a higher exposure risk via ingestion of leafy vegetable than rice. In the experiment, the researchers used many compounds, for example, Dicyclohexyl phthalate (cas: 84-61-7Computed Properties of C20H26O4).

Dicyclohexyl phthalate (cas: 84-61-7) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Computed Properties of C20H26O4

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

General and Chemoselective N-Transacylation of Secondary Amides by Means of Perfluorinated Anhydrides was written by Rota, Paola;Allevi, Pietro;Colombo, Raffaele;Costa, Maria L.;Anastasia, Mario. And the article was included in Angewandte Chemie, International Edition in 2010.HPLC of Formula: 6730-10-5 This article mentions the following:

The utility of chemoselective N-transacylation of secondary amides has a broad scope in synthetic chem. Secondly, the two-step replacement of acyl groups of secondary amides with a different on through the formation of a trifluoro intermediate allows one to prepare simple acyl analogs of a variety of pharmaceutical interest. Further, this reaction is useful in anal. protocols where N-transacylation can be overlooked due to puzzling results. In the experiment, the researchers used many compounds, for example, (2S,3S,4R,5S,6R)-3-Acetamido-6-(acetoxymethyl)tetrahydro-2H-pyran-2,4,5-triyl triacetate (cas: 6730-10-5HPLC of Formula: 6730-10-5).

(2S,3S,4R,5S,6R)-3-Acetamido-6-(acetoxymethyl)tetrahydro-2H-pyran-2,4,5-triyl triacetate (cas: 6730-10-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.HPLC of Formula: 6730-10-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Multiple Stimuli-Responsiveness Fluorescent Probe Derived from Cyclopolymers and Pyrene-Ended Ammonium Salts was written by Wang, Songmeng;Yang, Yi;Shi, Xiaoyu;Liu, Lingyan;Chang, Weixing;Li, Jing. And the article was included in ACS Applied Polymer Materials in 2020.Product Details of 27249-90-7 This article mentions the following:

A multiple stimuli-responsiveness fluorescent probe was fabricated by host-guest recognition between cyclopolymers with larger pseudo crown ether cavities in backbones and pyrene-ended ammonium salts. And this fluorescent probe exhibits ratiometric responsiveness to chloride anion, organic base, and temperature, as well as a dual luminescence responsiveness to nitro-compounds These properties of this probe endow it with potential application in multiple stimuli-responsive chem. fluorescent sensors. Moreover, it was found that the cyclopolymers with pyrenes grafted on the backbone increased excimer/monomer emission ratio of the fluorescent polypseudorotaxane, which would be expected to present higher sensitivity and responsiveness to external environment or stimuli-factors. In the experiment, the researchers used many compounds, for example, Benzyl benzodithioate (cas: 27249-90-7Product Details of 27249-90-7).

Benzyl benzodithioate (cas: 27249-90-7) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Product Details of 27249-90-7

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The competitive rates of reaction of a series of substituted benzyl methyl ethers with N-bromosuccinimide was written by Lovins, R. E.;Andrews, L. J.;Keefer, R. M.. And the article was included in Journal of Organic Chemistry in 1965.Computed Properties of C10H12O3 This article mentions the following:

The relative rates of reaction of a series of nuclear-substituted benzyl methyl ethers (XC₆H₄CH₂OCH₃) with N-bromosuccinimide in carbon tetrachloride are not highly sensitive to the influence of ring substituents. The small variations in substituent effects observed for the reaction do not parallel those expected for a transition state involving development of negative charge on the benzylic carbon but rather favor a transition state involving positive polarization of the reaction center. On the basis of the substituent effects observed in the reaction of benzyl methyl ethers with N-bromosuccinimide and the results of a determination of the relative rates of reaction of p-nitro- and p-methoxyethylbenzene (XC₆H₄CH₂CH₃) and of p-methoxybenzyl cyanide (p-CH₃OC₆H₄CH₂CN) with N-bromosuccinimide, it has been concluded that the magnitude of the effect of a ring substituent X on the benzyl hydrogen abstraction process is controlled primarily by the ability of the group Y to contribute to the intrinsic stability of the radical (XC₆H₄CHY) being formed in the activation process. In the experiment, the researchers used many compounds, for example, Methyl 2-methoxy-4-methylbenzoate (cas: 81245-24-1Computed Properties of C10H12O3).

Methyl 2-methoxy-4-methylbenzoate (cas: 81245-24-1) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Computed Properties of C10H12O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Comprehensive two-dimensional gas chromatography as a powerful strategy for the exploration of Broas volatile composition was written by Bento-Silva, Andreia;Duarte, Noelia;Santos, Magda;Costa, Carina Pedrosa;Vaz Patto, Maria Carlota;Rocha, Silvia M.;Bronze, Maria Rosario. And the article was included in Molecules in 2022.Synthetic Route of C6H10O2 This article mentions the following:

Broa is a Portuguese maize bread with characteristic sensory attributes that can only be achieved using traditional maize varieties. This study intends to disclose the volatile compounds that are mainly associated with the baking process of broas, which can be important contributors to their aroma. Twelve broas were prepared from twelve maize flours (eleven traditional maize varieties and one com. hybrid). Their volatile compounds were analyzed by GCxGC-ToFMS (two-dimensional gas chromatog. coupled with time-of-flight mass spectrometry) for an untargeted screening of the chem. compounds mainly formed during baking. It was possible to identify 128 volatiles that belonged to the main chem. families formed during this stage. Among these, only 16 had been previously detected in broas. The most abundant were furans, furanones, and pyranones, but the most relevant for the aroma of broas were ascribed to sulfur-containing compounds, in particular di-Me trisulfide and methanethiol. Pyrazines might contribute neg. to the aroma of broas since they were present in higher amounts in the com. broa. This work constitutes the most detailed study of the characterization of broas volatile compounds, particularly those formed during the Maillard reaction. These findings may contribute to the characterization of other maize-based foodstuffs, ultimately improving the production of foods with better sensory features. In the experiment, the researchers used many compounds, for example, 5-Ethyldihydrofuran-2(3H)-one (cas: 695-06-7Synthetic Route of C6H10O2).

5-Ethyldihydrofuran-2(3H)-one (cas: 695-06-7) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Synthetic Route of C6H10O2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Reformatsky and Blaise reactions in flow as a tool for drug discovery: one pot diversity oriented synthesis of valuable intermediates and heterocycles was written by Huck, L.;Berton, M.;de la Hoz, A.;Diaz-Ortiz, A.;Alcazar, J.. And the article was included in Green Chemistry in 2017.Recommanded Product: Ethyl 3-oxo-3-(thiophen-2-yl)propanoate This article mentions the following:

The application of Reformatskii and Blaise reactions for the preparation of a diverse set of valuable intermediates and heterocycles, e.g., I in a one-pot protocol was described. To achieve this goal, a greener activation protocol for zinc in flow conditions was developed to introduce this metal efficiently into α-bromoacetates. The organozinc compounds were added to a diverse set of ketones and nitriles to obtain a wide range of functional groups and heterocyclic systems. In the experiment, the researchers used many compounds, for example, Ethyl 3-oxo-3-(thiophen-2-yl)propanoate (cas: 13669-10-8Recommanded Product: Ethyl 3-oxo-3-(thiophen-2-yl)propanoate).

Ethyl 3-oxo-3-(thiophen-2-yl)propanoate (cas: 13669-10-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Recommanded Product: Ethyl 3-oxo-3-(thiophen-2-yl)propanoate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics