Silver-catalyzed three-component reaction of phenyldiazoacetate with arylamine and imine was written by Chen, Bai-Ling;Wang, Zhen;Zhang, You-Can;Zhao, Zhi-Gang;Chen, Zili. And the article was included in Chinese Journal of Catalysis in 2018.Related Products of 19432-68-9 This article mentions the following:
A new method was developed to diastereoselectively synthesize polysubstituted 1,2-diamine compounds from the reaction of diazoesters with arylamines and diaryl imines by using the dioxazoline ligand L2-ligated silver catalyst. The Lewis acidity of the silver catalyst affected the different types of substrate diastereoselectivities; It also led to the formation of amine-exchange side products. In the experiment, the researchers used many compounds, for example, Methyl 2-thienylacetate (cas: 19432-68-9Related Products of 19432-68-9).
Methyl 2-thienylacetate (cas: 19432-68-9) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Related Products of 19432-68-9
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics