Nilles, Katja et al. published their research in Polymer Chemistry in 2011 | CAS: 27249-90-7

Benzyl benzodithioate (cas: 27249-90-7) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Related Products of 27249-90-7

Polymerization of an activated ester monomer based on 4-vinylsulfonic acid and its polymer analogous reaction was written by Nilles, Katja;Theato, Patrick. And the article was included in Polymer Chemistry in 2011.Related Products of 27249-90-7 This article mentions the following:

Homopolymers containing sulfonic ester side groups were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization utilizing benzyl dithiobenzoate, cumyl dithiobenzoate, and 4-cyano-4-((thiobenzoyl)sulfanyl)pentanoic acid as chain transfer agents. Likewise diblock copolymers containing poly(styrene), poly(octylstyrene) and poly(pentafluorostyrene) as the second block were synthesized. Addnl., nitroxide mediated polymerization (NMP) was investigated for the synthesis of a homopolymer as well as for a diblock copolymer. Furthermore, the post-polymerization functionalization with various amines to yield the resp. sulfonamides was conducted. The conversion was analyzed by 1H NMR spectroscopy, 19F NMR spectroscopy and FT-IR spectroscopy and in many cases a very high conversion (>96%) was observed In addition the reaction kinetics of the post-polymerization functionalization of poly(pentafluorophenyl 4-vinylbenzene sulfonate) and the corresponding carboxyl ester poly(pentafluorophenyl 4-vinylbenzoate) were compared by anal. of the reactions by time-resolved 19F NMR spectroscopy. It was found that poly(pentafluorophenyl 4-vinylbenzoate) showed a higher stability towards hydrolysis and a significantly higher reactivity, resulting in complete conversions with different amines. In the experiment, the researchers used many compounds, for example, Benzyl benzodithioate (cas: 27249-90-7Related Products of 27249-90-7).

Benzyl benzodithioate (cas: 27249-90-7) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Related Products of 27249-90-7

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics