Iron-Catalyzed Hydrosilylation of Esters was written by Bezier, David;Venkanna, Gopaladasu T.;Castro, Luis C. Misal;Zheng, Jianxia;Roisnel, Thierry;Sortais, Jean-Baptiste;Darcel, Christophe. And the article was included in Advanced Synthesis & Catalysis in 2012.COA of Formula: C7H8O2S This article mentions the following:
The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcs. at 100 °C, under solvent-free conditions and visible light activation. E.g., in presence of [CpFe(PCy3)(CO)2]BF4, hydrosilylation of 4-MeC6H4CH2CO2Me gave 70% 4-MeC6H4CH2CH2OH. PhSiH3 was used as the reductant. In the experiment, the researchers used many compounds, for example, Methyl 2-thienylacetate (cas: 19432-68-9COA of Formula: C7H8O2S).
Methyl 2-thienylacetate (cas: 19432-68-9) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.COA of Formula: C7H8O2S
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics