Malkov, Andrei V. et al. published their research in Chemistry – A European Journal in 2008 | CAS: 13669-10-8

Ethyl 3-oxo-3-(thiophen-2-yl)propanoate (cas: 13669-10-8) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Category: esters-buliding-blocks

Dynamic kinetic resolution in the asymmetric synthesis of β-amino acids by organocatalytic reduction of enamines with trichlorosilane was written by Malkov, Andrei V.;Stoncius, Sigitas;Vrankova, Kvetoslava;Arndt, Matthias;Kocovsky, Pavel. And the article was included in Chemistry – A European Journal in 2008.Category: esters-buliding-blocks This article mentions the following:

A new, expedient protocol has been developed for the asym. synthesis of β3– and β2,3-amino acid derivatives from enamine precursors. The method relies on a fast equilibrium between the enamine and imine forms. Reduction of the imine with Cl3SiH, catalyzed by the L-valine-derived formamide, OHCN(Me)CH(iso-Pr)CONHC6H3(tert-Bu)2-3,5, (5 mol%), afforded the corresponding amino esters in good yields, good enantioselectivities (â‰?0% ee) and high diastereoselectivities (â‰?9% de). In the experiment, the researchers used many compounds, for example, Ethyl 3-oxo-3-(thiophen-2-yl)propanoate (cas: 13669-10-8Category: esters-buliding-blocks).

Ethyl 3-oxo-3-(thiophen-2-yl)propanoate (cas: 13669-10-8) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics