Synthesis of functionalized S-benzyl dithiocarbamates from diazo-compounds via multi-component reactions with carbon disulfide and secondary amines was written by Kumar, Nitin;Venkatesh, Rapelly;Kandasamy, Jeyakumar. And the article was included in Organic & Biomolecular Chemistry in 2022.Recommanded Product: 584-74-7 This article mentions the following:
Triflic acid promoted multi-component synthesis of functionalized S-benzyl dithiocarbamates R1CH(C(O)R2)(SC(S)NR3R4) [R1 = Ph, 2-fluorophenyl, 4-methylphenyl, etc.; R2 = OEt, OMe, Oi-Pr, Ot-Bu, cyclohexyloxy; R3 = H, Et, Pr, hexyl; R4 = Et, Pr, Bu, hexyl, benzylmethyl; R3R4 = -(CH2)4-, -(CH2)5-, -(CH2)2O(CH2)2-, -(CH2)2S(CH2)2-, -(CH2)2N(Me)(CH2)2-] from diazo compounds R1C(=N2)C(O)R2, carbon disulfide and secondary amines R3R4NH is reported. The reactions proceeded at room temperature and gave the desired S-benzyl dithiocarbamates in good yields. Wide-substrate scope and easy operation are the important features of this methodol. In the experiment, the researchers used many compounds, for example, Ethyl 2-fluorophenylacetate (cas: 584-74-7Recommanded Product: 584-74-7).
Ethyl 2-fluorophenylacetate (cas: 584-74-7) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Recommanded Product: 584-74-7
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics