Reactivity and Catalytic Activity of Homobimetallic Vanadium(V) Complex Derived from Bis(5-chlorosalicylaldehyde)oxaloyldihydrazone Ligand was written by Syiemlieh, Ibanphylla;Asthana, Mrityunjaya;Lal, Ram A.. And the article was included in Applied Organometallic Chemistry in 2019.Computed Properties of C9H10O3 This article mentions the following:
Homobimetallic vanadium(V) complex of the composition [(CH3)2NH2+]2[(VO2)2(sloxCl)].4H2O was synthesized from the reaction of V2O5 with bis(5-chlorosalicylaldehyde)oxaloyldihydrazone ligand in a 1:1 molar ratio in methanol. The structure of the complex was established by x-ray crystallog. Reactivity of the complex with H2O2 leads to bis (monooxidoperoxidovanadate(V)) [{VO(O2)}2(sloxCl)]2- formation and with HCl, oxidohydroxido complex of composition [(VO) (OH)(sloxCl)]2- was formed. Binding interaction of the complex was also investigated toward protein (BSA) and it is 2.21 × 108 M-1. The catalytic activity of the complex in the oxidation of alcs. and oxidative bromination of some organic substrates was also studied, and it showed a great potent as a catalyst. In the experiment, the researchers used many compounds, for example, Ethyl 2-hydroxybenzoate (cas: 118-61-6Computed Properties of C9H10O3).
Ethyl 2-hydroxybenzoate (cas: 118-61-6) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Computed Properties of C9H10O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics