Rhodium(III)-catalyzed sulfonamide directed ortho C-H carbenoid functionalization via metal carbene migratory insertion was written by Dong, Yi;Chen, Jiajing;Xu, Heng. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Application In Synthesis of Methyl 2-(methylsulfonyl)acetate This article mentions the following:
A rhodium(III)-catalyzed sulfonamide directed ortho C-H carbenoid functionalization was developed with good yields. This method was attractive due to its broad substrate scope and enabled derivation of diverse biol. active sulfonamide structures and late-stage modification of sulfa drugs. In the experiment, the researchers used many compounds, for example, Methyl 2-(methylsulfonyl)acetate (cas: 62020-09-1Application In Synthesis of Methyl 2-(methylsulfonyl)acetate).
Methyl 2-(methylsulfonyl)acetate (cas: 62020-09-1) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Application In Synthesis of Methyl 2-(methylsulfonyl)acetate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics