Qin, Qixue published the artcileA metal-free desulfurizing radical reductive C-C coupling of thiols and alkenes, Quality Control of 19788-49-9, the publication is Chemical Communications (Cambridge, United Kingdom) (2019), 55(71), 10583-10586, database is CAplus and MEDLINE.
An intermol. reductive C-C coupling of electrophilic alkyl radicals and alkenes was developed. Thiols were used as both hydrogen-donating reagents and alkyl radical precursors in the presence of tri-Et phosphite and radical initiator. A wide range of alkenes, including styrenes and aliphatic olefins were well tolerated in this transformation. Mechanistic studies indicated that a phosphite promoted radical desulfurization of thiols to accessed electrophilic alkyl radicals and a radical chain propagation process may be involved in this transformation.
Chemical Communications (Cambridge, United Kingdom) published new progress about 19788-49-9. 19788-49-9 belongs to esters-buliding-blocks, auxiliary class Thiol,Aliphatic hydrocarbon chain,Ester, name is Ethyl 2-mercaptopropanoate, and the molecular formula is C5H10O2S, Quality Control of 19788-49-9.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics