Lombardi, Lorenzo published the artcileAllylic and Allenylic Dearomatization of Indoles Promoted by Graphene Oxide by Covalent Grafting Activation Mode, Formula: C7H12O3, the main research area is indole arylpropenol graphene oxide regioselective diastereoselective allylation dearomatization; arylpropenyl indole preparation green chem; arylpropynol indole graphene oxide regioselective diastereoselective allenylation dearomatization; arylallenyl indole preparation green chem; alcohols; carbocatalysis; dearomatization; graphene oxide; indole.
The site-selective allylative and allenylative dearomatization of indoles with alcs. was performed under carbocatalytic regime in the presence of graphene oxide (GO, 10 wt % loading) as the promoter. Metal-free conditions, absence of stoichiometric additive, environmentally friendly conditions (H2O/CH3CN, 55 C, 6 h), broad substrate scope (33 examples, yield up to 92%) and excellent site- and stereoselectivity characterize the present methodol. Moreover, a covalent activation model exerted by GO functionalities was corroborated by spectroscopic, exptl. and computational evidences. Recovering and regeneration of the GO catalyst through simple acidic treatment was also documented.
Chemistry – A European Journal published new progress about Alcohols, propargyl Role: RCT (Reactant), RACT (Reactant or Reagent). 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, Formula: C7H12O3.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics