Treacy, Sean M. published the artcileCopper Catalyzed C(sp3)-H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer, Recommanded Product: Dimethyl adipate, the publication is Journal of the American Chemical Society (2021), 143(7), 2729-2735, database is CAplus and MEDLINE.
The functionalization of numerous feedstock chems. via the coupling of unactivated C(sp3)-H bonds with electron-deficient olefins was reported. The active cuprate catalyst undergoes ligand-to-metal charge transfer enabled the generation of a chlorine radical which acted as a powerful hydrogen atom transfer reagent capable of abstracting strong electron-rich C(sp3)-H bonds. Of note is that the chlorocuprate catalyst was an exceedingly mild oxidant (0.5 V vs SCE) and that a proposed protodemetalation mechanism offered a broad scope of electron-deficient olefins, offered high diastereoselectivity in the case of endocyclic alkenes. The coupling of chlorine radical generation with Cu reduction through LMCT enabled the generation of a highly active HAT reagent in an operationally simple and atom economical protocol.
Journal of the American Chemical Society published new progress about 627-93-0. 627-93-0 belongs to esters-buliding-blocks, auxiliary class Ploymers, name is Dimethyl adipate, and the molecular formula is C12H17NO2, Recommanded Product: Dimethyl adipate.
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https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics