Zheng, Xiu-Cheng published the artcilePreparation and catalytic performance of tungstophosphoric acid anchored to SiO2@graphene aerogel 3D porous catalysts for the synthesis of ethyl levulinate biofuel, Related Products of esters-buliding-blocks, the main research area is ethyl levulinate biofuel esterification catalyst levulinic acid ethanol; tungstophosphoric acid silica graphene aerogel porous catalyst.
As fuel additives, Et levulinate (EL) can be used up to 5 wt% directly in the regular diesel engines, which can overcome the limited stock of fossil fuels and reduce the environment pollutions to some extent. In this work, the three-dimensional porous hybrids consisting of SiO2 and graphene aerogel, which are denoted as SiO2@GA, are facilely assembled and used as supports for H3PW12O40 (HPW)-based solid acid catalysts. Structural anal. confirms that the resultant HPW/SiO2@GA catalysts possess unique porous structure (SBET ≥ 257 m2 g-1, Vp ≥ 0.450 cm3 g-1) and exhibit excellent catalytic performance in the synthesis of EL by the esterification of levulinic acid (LA) with ethanol. The conversion of LA can be as high as 92.4% under the reaction conditions. Furthermore, various catalytic reaction parameters are also optimized over the 10 weight% HPW/SiO2@GA catalysts, which exhibit the highest turnover frequency (TOF = 83.91 mmol g-1 h-1) among the resultant catalysts. The results confirm the promising application of the HPW/SiO2@GA heterogeneous catalysts in the synthesis of biofuel.
Journal of Porous Materials published new progress about Aerogels. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, Related Products of esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics