Liu, Zhong-Qiu published the artcileCatalytic hydroconversion of Yiwu lignite over solid superacid and solid superbase, Category: esters-buliding-blocks, the main research area is lignite solid superacid superbase catalytic hydroconversion.
Trifluoromethanesulfonic acid supported on attapulgite powder (TFMSA/AP) and Mg2Si/γ-Al2O3 were facilely prepared by impregnating TFMSA onto AP and Mg2Si onto γ-Al2O3. The extraction residue from Yiwu lignite (YLER) was subjected to non-catalytic hydroconversion (NCHC) and catalytic hydroconversion (CHC) over TFMSA/AP and Mg2Si/γ-Al2O3, resp. Detailed mol. compositions of the soluble portions from the NCHC (SPNCHC) and CHC over TFMSA/AP (SPCHC-A) and Mg2Si/γ-Al2O3 (SPCHC-B) were characterized with a gas chromatograph/mass spectrometer. As a result, the yields of SPCHC-A and SPCHC-B are 19.6% and 17.5%, resp., which are much higher than that of SPNCHC (1.04%), suggesting that both TFMSA/AP and Mg2Si/γ-Al2O3 show excellent activity for the CHC of YLER. Arenes and arenols are predominant in SPCHC-A and SPCHC-B, resp., while large amounts of alkanoates were detected in SPNCHC. The results indicate that TFMSA/AP effectively catalyzes the cleavage of Car-Calk and Calk-O bridged bonds (BBs) in YLER, while Mg2Si/γ-Al2O3 significantly promotes the cleavage of C-O BBs in YLER. Di(1-naphthyl)methane, 1-methylnaphthalene, oxydibenzene, and benzyloxybenzene were used as coal-related model compounds (CRMCs) for the CHC to further explore the catalysis of TFMSA/AP and Mg2Si/γ-Al2O3. The results show that TFMSA/AP not only releases mobile H+ but also heterolytically splits H2 to form an immobile H- and a mobile H+, leading to the cleavage of Calk-Car and Calk-O BBs in the CRMCs. In contrast, Mg2Si/γ-Al2O3 facilitates heterolytically splitting H2 to an immobile H+ and a mobile H-, resulting in the cleavage of C-O BBs in the CRMCs.
Fuel published new progress about Catalysts. 123-29-5 belongs to class esters-buliding-blocks, name is Ethyl nonanoate, and the molecular formula is C11H22O2, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics