Liao, Pei-Han published the artcileOn-Line Coupling of Simultaneous Distillation-Extraction Using the Likens-Nickerson Apparatus with Gas Chromatography, Formula: C17H34O2, the main research area is coupling simultaneous distillation extraction gas chromatograph mass spectrometer ester.
Simultaneous distillation-extraction (SDE) using the Likens-Nickerson apparatus is a convenient technique used to isolate volatile organic compounds (VOCs) from complex liquid matrixes. The technique combines steam distillation with solvent extraction While anal. extractions are normally followed by off-line separation/detection, it is advantageous to couple extractions online with separation and detection systems that are employed in the same anal. workflow. Here, we have coupled the Likens-Nickerson apparatus online with a gas chromatograph hyphenated with a mass spectrometer. For that purpose, we have devised an automated liquid transfer setup comprising a peristaltic pump, control unit, customized transfer vial with a drain port, and an autosampler arm to deliver liquid extract aliquots at defined time points. The online SDE-GC/MS system enables one to record real-time extraction profiles. These profiles reveal extraction kinetics of various VOCs present in the extracted samples. The data sets were fitted with the first order kinetic equation to obtain numeric values characterizing the extraction process (rate constants ranging from 0.21 to 0.01 min-1 for the Et esters from C6 to C19). A comparison of online and off-line results reveals that the online system is more dependable, while the off-line anal. leads to artifacts. To demonstrate the operation of the online SDE-GC/MS system, we performed analyses of selected real samples (beer). The real-time data sets revealed extraction kinetics for VOCs present in these samples. The devised extraction-anal. system allows the analysts to make an evidence-based decision on the extraction time for different groups of analytes in order to maximize extraction yield and minimize analyte losses.
Analytical Chemistry (Washington, DC, United States) published new progress about Beer. 41114-00-5 belongs to class esters-buliding-blocks, name is Ethyl pentadecanoate, and the molecular formula is C17H34O2, Formula: C17H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics