Levi, Samuel M. published the artcileCatalytic activation of glycosyl phosphates for stereoselective coupling reactions, Recommanded Product: Benzyl acetate, the main research area is stereoselective coupling catalytic glycoside preparation nucleophilic substitution thiourea; H bonding; glycosylation; organocatalysis; phosphate.
Glycosyl phosphates are shown to be activated to stereospecific nucleophilic substitution reactions by precisely tailored bis-thiourea catalysts. Enhanced reactivity and scope is observed with phosphate relative to chloride leaving groups. Stronger binding (Km) to the H-bond donor and enhanced reactivity of the complex (kcat) enables efficient catalysis with broad functional group compatibility under mild, neutral conditions.
Proceedings of the National Academy of Sciences of the United States of America published new progress about Catalysis. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Recommanded Product: Benzyl acetate.
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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics