Rodriguez, Jessica published the artcileAu(I)/Au(III) Catalytic Allylation Involving π-Allyl Au(III) Complexes, Formula: C10H10O2, the main research area is branched allylated indole preparation; allyl compound indole cross coupling gold catalyst.
A (MeDalphos)AuCl complex was found to efficiently catalyze the cross-coupling of indoles and allyl acetates/alcs. The reaction tolerated many functional groups and selectively affords the branched C3-allylated products from both α- and γ-substituted allyl substrates. It took the advantage of the hemilabile character of the PN ligand. The C(sp2)-C(sp3) coupling operated via a Au(I)/Au(III) redox cycle and involves a dicationic π-allyl Au(III) complex as a key intermediate. In this case, the allyl moiety adopted an asym. σ + π-coordination mode, as substantiated by NMR spectroscopy and d. functional theory (DFT) calculations
ACS Catalysis published new progress about Cross-coupling reaction. 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Formula: C10H10O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics