Nolla-Saltiel, Roberto published the artcileHydrophosphination of Activated Alkenes by a Cobalt(I) Pincer Complex, SDS of cas: 627-93-0, the publication is Advanced Synthesis & Catalysis (2020), 362(15), 3148-3157, database is CAplus.
Herein is reported the synthesis of three heteroleptic first-row transition metal(II) complexes containing carbazolido NNN pincer ligands and conversion to the corresponding metal(I)-carbonyl complexes via a reductive carbonylation route. These complexes are precatalysts for the hydrophosphination of activated alkenes, affording a cobalt-catalyzed hydrophosphination process that solely and selectively yields the β addition (anti-Markovnikov) product. The scope of this transformation has been investigated using a variety of activated alkenes. Isolation and characterization of substrate-coordinated intermediates reveal available coordination sites, which provide insight into the proposed catalytic cycle.
Advanced Synthesis & Catalysis published new progress about 627-93-0. 627-93-0 belongs to esters-buliding-blocks, auxiliary class Ploymers, name is Dimethyl adipate, and the molecular formula is C8H14O4, SDS of cas: 627-93-0.
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https://en.wikipedia.org/wiki/Ester,
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