Kinetic polymerization behavior of fluorinated monomers for dental use was written by Kadoma, Yoshinori. And the article was included in Dental Materials Journal in 2010.Product Details of 3063-94-3 The following contents are mentioned in the article:
The kinetic polymerization behavior of 2,2,2-trifluoroethyl methacrylate (TFEMA), 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA), 2,2,2-trifluoroethyl acrylate (TFEA), and 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) was determined by isothermal differential scanning calorimetry (DSC) and high-performance liquid chromatog. (HPLC) in order to improve the properties of fluorinated powder-liquid adhesive resins. Conversion and heat of polymerization were calculated, and the solubility of the homopolymers in common solvents was examined Comparison of their polymerization reactivity with that of MMA revealed that the overall rate of polymerization initiated by benzoyl peroxide (BPO) decreased in the order TFEA > MMA > TFEMA > HFIPA > HFIPMA. Based on the retention time of the monomer determined by HPLC, the hydrophobicity of the monomers was found to increase in the order MMA < TFEA < TFEMA < HFIPA < HFIPMA. The overall research results suggested that TFEA and HFIPA would be potentially promising candidates for the monomer liquid component of fluorinated powder-liquid adhesive resins. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Product Details of 3063-94-3).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Product Details of 3063-94-3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics