Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates was written by Semenova, Anna M.;Ezhikova, Marina A.;Kodess, Mikhail I.;Zapevalov, Aleksandr Ya.;Pestov, Aleksandr V.. And the article was included in Mendeleev Communications in 2021.Recommanded Product: Diphenyl carbonate The following contents are mentioned in the article:
A phosgene-free synthesis of sym. bis(polyfluoroalkyl) carbonates H(CF2CF2)nCH2OC(O)COCH2(CF2CF2)nH (n = 1, 2, 3) involves the transesterification of di-Ph carbonate with polyfluoroalkanols H(CF2CF2)nCH2OH promoted by stoichiometric amounts of titanium(iv) alkoxides Ti(OR)4 (R = Et, n-Bu, i-Pr). This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Recommanded Product: Diphenyl carbonate).
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Recommanded Product: Diphenyl carbonate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics