B(C6F5)3-Catalyzed transfer hydrogenation of esters and organic carbonates towards alcohols with ammonia borane was written by Guo, Xuewen;Unglaube, Felix;Kragl, Udo;Mejia, Esteban. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2022.SDS of cas: 102-09-0 The following contents are mentioned in the article:
Herein, authors report an efficient metal-free system for the transfer hydrogenation of esters and carbonates by-passing the otherwise ubiquitous formation of transesterification side-products. The Lewis acid B(C6F5)3 is used as catalyst and ammonia borane as hydrogen donor. This methodol. shows broad substrate scope and functional group tolerance in excellent yields at very mild conditions. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0SDS of cas: 102-09-0).
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.SDS of cas: 102-09-0
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics