Cooperative copper-squaramide catalysis for the enantioselective N-H insertion reaction with sulfoxonium ylides was written by Furniel, Lucas G.;Echemendia, Radell;Burtoloso, Antonio C. B.. And the article was included in Chemical Science in 2021.Related Products of 102-09-0 The following contents are mentioned in the article:
The first examples of a highly efficient and enantioselective carbene-mediated insertion reaction, from a sulfur ylide, were described. By way of a catalytic asym. insertion reaction into N-H bonds from carbonyl sulfoxonium ylides and anilines, using a copper-bifunctional squaramide cooperative catalysis approach, thirty-seven α-arylglycine esters were synthesized in enantiomeric ratios up to 92:8 (99:1 after a single recrystallization) and reaction yields ranging between 49-96%. Furthermore, the protocol benefited from quick reaction times and was conducted in a straightforward manner. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Related Products of 102-09-0).
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Related Products of 102-09-0
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics