A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane was written by Fukuyama, Takahide;Hamada, Yuki;Ryu, Ilhyong. And the article was included in Synthesis in 2021.Application of 112-14-1 The following contents are mentioned in the article:
The reduction of alkyl/aryl chlorides RX (R = n-dodecyl, adamantan-1-yl, naphthalen-1-yl, etc.) using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C-Cl bonds were effectively converted into C-H bonds using [IrCl(cod)]2/2,6-bis(benzimidazol-2-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from com. available reagents. This study involved multiple reactions and reactants, such as Octyl acetate (cas: 112-14-1Application of 112-14-1).
Octyl acetate (cas: 112-14-1) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Application of 112-14-1
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics