Enantioselective palladaelectro-catalyzed C-H olefinations and allylations for N-C axial chirality was written by Dhawa, Uttam;Wdowik, Tomasz;Hou, Xiaoyan;Yuan, Binbin;Oliveira, Joao C. A.;Ackermann, Lutz. And the article was included in Chemical Science in 2021.Reference of 3063-94-3 The following contents are mentioned in the article:
Enantioselective palladaelectro-catalyzed C-H alkenylations and allylations were achieved with easily-accessible amino acids as transient directing groups. This strategy provided access to highly enantiomerically-enriched N-C axially chiral scaffolds under exceedingly mild conditions. The synthetic utility of the above strategy was demonstrated by a variety of alkenes, while the versatility of the approach was reflected by atroposelective C-H allylations. Computational studies provided insights into a facile C-H activation by a seven-membered palladacycle. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Reference of 3063-94-3).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Reference of 3063-94-3
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Ester – an overview | ScienceDirect Topics