Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals was written by Angeloski, Alexander;Cortie, Michael B.;Scott, John A.;Bordin, Dayanne M.;McDonagh, Andrew M.. And the article was included in Inorganica Chimica Acta in 2019.Application of 2253-73-8 The following contents are mentioned in the article:
Single crystals of bis(κ2S,S’-di(isopropyl)dithiocarbamato) Ni(II) were used as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at ∼250° to form α-NiS exclusively with no β-NiS detected. Anal. of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and CS2. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relations. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Application of 2253-73-8).
Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Application of 2253-73-8
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics