Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals was written by Angeloski, Alexander;Cortie, Michael B.;Scott, John A.;Bordin, Dayanne M.;McDonagh, Andrew M.. And the article was included in Inorganica Chimica Acta in 2019.Application of 2253-73-8 The following contents are mentioned in the article:
Single crystals of bis(κ2S,S’-di(isopropyl)dithiocarbamato) Ni(II) were used as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at ∼250° to form α-NiS exclusively with no β-NiS detected. Anal. of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and CS2. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relations. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Application of 2253-73-8).
Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Application of 2253-73-8
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics