Otsu, Takayuki published the artcileLiving mono- and biradical polymerizations in homogeneous system synthesis of AB and ABA type block copolymers, Product Details of C12H17NS2, the publication is Polymer Bulletin (Berlin, Germany) (1984), 11(2), 135-42, database is CAplus.
To design the structure of the block copolymers by radical polymerization benzyl N,N-diethyldithiocarbamate (I) [3052-61-7] and P-xylylene N,N-diethyldithiocarbamate (II) [89964-93-2] were used as mono- and bifunctional photo-iniferters, resp., for the polymerizations of styrene and Me methacrylate. These polymerizations proceeded via a living radical mechanism. When the ratio of the concentration of the diethyldithiocarbamate group to that of a photo-iniferter mol. was kept constant, the yields of the polymers obtained by both I and II were identical, and their mol. weights(M) by II were 2 times as high as those by I. This observation strongly suggested that the polymerizations by I and II were performed by living mono- and biradical mechanisms, resp. By using the polymers obtained by I and II as polymeric photo-iniferters of the polymerization of second monomers, the AB and ABA-type block copolymers [25034-86-0] were obtained, resp.
Polymer Bulletin (Berlin, Germany) published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Product Details of C12H17NS2.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics