Mijangos, Irene published the artcileMacroradical initiated polymerization of acrylic and methacrylic monomers, Name: Benzyl diethylcarbamodithioate, the publication is Journal of Separation Science (2009), 32(19), 3340-3346, database is CAplus and MEDLINE.
An approach has been developed for the grafting of monomers onto poly(trimethylolpropane trimethacrylate) (polyTRIM) particles using 2,2-di-Et dithiocarbamic acid benzyl ester (DDCABE) as an initiator. A set of polymers was prepared with this technique over different lengths of time and the kinetics of the reaction studied exptl. It was found that the grafting of initiator to the polymeric support followed a second order reaction, while the subsequent addition of monomers from solution into the polyTRIM macroradicals followed a first order reaction. The living nature of the iniferter modified macroradicals permits easy consecutive grafting of multiple polymeric layers, allowing straightforward functionalization of particles. However, the effectiveness of the grafted initiator decreased with each cycle of polymerization This technique can be used for a wide range of applications in anal. and biochem.
Journal of Separation Science published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Name: Benzyl diethylcarbamodithioate.
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