Li, Siqi et al. published their research in Reactive & Functional Polymers in 2022 | CAS: 102-09-0

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Reference of 102-09-0

Lipase-catalyzed ring-opening copolymerization of macrocycles for diselenide-functionalized long-chain polycarbonate: Synthesis, kinetic process and ROS responsiveness was written by Li, Siqi;Ma, Xiaotong;Li, Ruizhi;Sun, Chuanhao;Hu, Jieni;Zhang, Yan. And the article was included in Reactive & Functional Polymers in 2022.Reference of 102-09-0 The following contents are mentioned in the article:

Herein, the lipase-catalyzed ring-opening copolymerization of the diethylene diselenide carbonate dimer (SeC) with its analog macrocycle (1,3,12,14-Tetraoxacyclodocosane-2,13-dione, TDC) was explored, and the small-ring carbonate (TMC) was used as control. The structure and composition of the diselenide-functionalized long-chain polycarbonates were confirmed by NMR and FTIR. The 13C NMR and 77Se NMR showed that the copolymers observed random sequence. Moreover, the kinetic process of TDC + SeC copolymerization demonstrated a faster polymerization rate and higher conversion of SeC in comparison with TMC + SeC. Besides, the copolymers exhibited ROS-responsive behaviors when exposed to the oxidizing environment owing to the diselenide groups, which was confirmed by UV-vis, DLS and TEM. Therefore, the ROS responsiveness facilitated potential application for the diselenide-functionalized copolymers. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Reference of 102-09-0).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Reference of 102-09-0

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics