Ha, Deok Chan’s team published research in Journal of the American Chemical Society in 106 | CAS: 5340-78-3

Journal of the American Chemical Society published new progress about 5340-78-3. 5340-78-3 belongs to esters-buliding-blocks, auxiliary class Aliphatic Chain, name is Ethyltert-butylacetate, and the molecular formula is C8H16O2, Formula: C8H16O2.

Ha, Deok Chan published the artcileN-Trimethylsilylimines: applications to the syntheses of β-lactams, Formula: C8H16O2, the publication is Journal of the American Chemical Society (1984), 106(17), 4819-25, database is CAplus.

Ester enolates and N-trimethylsilylimines react to afford β-lactams. The stereochem. course of the reaction depends on the ester enolate geometry. Thus, (E)-enolates give mainly cis β-lactams while (Z)-enolates give ∼1:1 mixtures of cis and trans β-lactams. The use of HOCHMeCH2CO2Et as the ester component gives β-lactams of potential use in carbapenem synthesis. The differences in the behavior of N-trimethylsilyl and N-arylimines in the ester-imine condensations are also discussed.

Journal of the American Chemical Society published new progress about 5340-78-3. 5340-78-3 belongs to esters-buliding-blocks, auxiliary class Aliphatic Chain, name is Ethyltert-butylacetate, and the molecular formula is C8H16O2, Formula: C8H16O2.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics