En Route to CO2-Based (a)Cyclic Carbonates and Polycarbonates from Alcohols Substrates by Direct and Indirect Approaches was written by Brege, Antoine;Grignard, Bruno;Mereau, Raphael;Detrembleur, Christophe;Jerome, Christine;Tassaing, Thierry. And the article was included in Catalysts in 2022.Synthetic Route of C13H10O3 The following contents are mentioned in the article:
A review. This review is dedicated to the state-of-the art routes used for the synthesis of CO2-based (a)cyclic carbonates and polycarbonates from alc. substrates, with an emphasis on their resp. main advantages and limitations. The first section reviews the synthesis of organic carbonates such as dialkyl carbonates or cyclic carbonates from the carbonation of alcs. Many different synthetic strategies have been reported (dehydrative condensation, the alkylation route, the “leaving group” strategy, the carbodiimide route, the protected alcs. route, etc.) with various substrates (mono-alcs., diols, allyl alcs., halohydrins, propargylic alcs., etc.). The second section reviews the formation of polycarbonates via the direct copolymerization of CO2 with diols, as well as the ring-opening polymerization route. Finally, polycondensation processes involving CO2-based di-Me and di-Ph carbonates with aliphatic and aromatic diols are described. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Synthetic Route of C13H10O3).
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Synthetic Route of C13H10O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics