Badet, B.’s team published research in Tetrahedron in 39 | CAS: 5205-11-8

Tetrahedron published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Name: 3-Methylbut-2-en-1-yl benzoate.

Badet, B. published the artcileEffect of copper salts on the alkylation of carboxylate ions by sulfonium salts, Name: 3-Methylbut-2-en-1-yl benzoate, the publication is Tetrahedron (1983), 39(19), 3111-25, database is CAplus.

BzOK, AcOK, and BzOH-K2CO3 were alkylated using sulfonium salts Ph2S+R, PhS+R1R2, R3S+R42, or R5R6S+CH2CH:CH2 [R = Me, Et, Pr, Bu, allyl, CHMe2, CH2Ph; R1, R6 = lauryl, Me; R2 = allyl, lauryl; R3 = Me, Pr, CHMe2, CMe3, allyl, methallyl, 2-octyl, prenyl, lauryl; R4 = Me, Pr, allyl, lauryl, (CH2)4,5; R5 = Et, Ph]. Mixtures of esters were obtained. In the presence of Cu(I) salts, the reaction of allylic sulfonium salts became very selective in favor of the unsaturated residues. Prenyl sulfonium salts, which reacted through the α-position in the absence of Cu salts, gave exclusively tertiary esters when a catalytic amount of CuBr was present.

Tetrahedron published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Name: 3-Methylbut-2-en-1-yl benzoate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics