Wang, Jiahao et al. published their research in Polymer Chemistry in 2020 | CAS: 102-09-0

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Application In Synthesis of Diphenyl carbonate

Ring opening copolymerization of e-caprolactone and diselenic macrolide carbonate for well-defined poly(ester-co-carbonate): kinetic evaluation and ROS/GSH responsiveness was written by Wang, Jiahao;Sun, Chuanhao;Hu, Jieni;Huang, Yanling;Lu, Yunxiang;Zhang, Yan. And the article was included in Polymer Chemistry in 2020.Application In Synthesis of Diphenyl carbonate The following contents are mentioned in the article:

A resurgence of interest has recently propelled poly(e-caprolactone) (PCL) back into the biomaterials arena. Herein, we reported a new poly(ester-co-carbonate) via the copolymerization of e-CL and a diselenic macrolide carbonate monomer (MSeSe). The structure of the copolymer was confirmed by NMR, FTIR and GPC. The kinetic exptl. studies showed that the monomer reactivity ratios of e-CL (r1) and MSeSe (r2) were different and the final sequence distribution of the copolymer was random, which agreed well with the theor. results based on d. functional theory (DFT) calculations The results of DSC and XRD consistently indicated that the copolymers were inclined to be amorphous with the increase in the MSeSe fraction. UV, DLS and TEM techniques were employed to demonstrate the variation of transmittance, size and the morphol. of copolymer micelles subjected to the GSH and ROS environments, and the mechanism was clarified by FTIR and GPC, which demonstrated that the copolymers had rich environment responsiveness. Therefore, poly(ester-co-carbonate) with higher ROS and GSH sensitivity has great potential in the biomaterials field. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Application In Synthesis of Diphenyl carbonate).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Application In Synthesis of Diphenyl carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics