Catalytic hydroboration of carbonyl derivatives by using phosphinimino amide ligated magnesium complexes was written by Li, Min;Liu, Xinli;Cui, Dongmei. And the article was included in Dalton Transactions in 2021.Related Products of 102-09-0 The following contents are mentioned in the article:
Reduction of carbonyl derivatives by using Earth-abundant, cheap, and environmentally benign metal-based catalysts through an atom-efficient method is a challenging task. Herein, authors report the synthesis and characterization of dinuclear magnesium complexes 1–3 chelated by a phosphinimino amide skeleton. In combination with pinacolborane (HBpin) as a reducing agent, complex 1 bearing an ortho-Me substituent on the Ph ring of the ligand showed excellent reduction capability for a broad range of carbonyl derivatives under mild reaction conditions. Aldehydes, ketones, and acrolein substrates were efficiently reduced to the corresponding alkoxy-borane products with a record high TOF. Besides, acrolein derivatives were exclusively reduced to 1,2-regioselective products. Using two equivalent of HBpin, ester substrates were reduced to two kinds of alkoxy-borane products. Carbonate reduction accomplished by using complex 1 and three equivalent of HBpin afforded diols and a methanol precursor, resp. When chiral substrates such as (S)-1,2-propanediol carbonate and
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Related Products of 102-09-0
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics