Synthesis of Aliphatic Hyperbranched Polycarbonates via Organo-Catalyzed “A1+B2“-Ring-Opening Polymerization was written by Wang, Chengliang;Zhang, Xu;Zhao, Wei;Liu, Xin;Wang, Qingfu;Sun, Jingjiang. And the article was included in Macromolecules (Washington, DC, United States) in 2022.Synthetic Route of C13H10O3 The following contents are mentioned in the article:
Hyperbranched aliphatic polycarbonates (HBPCs) have attracted significant attention in the field of biomedical application owing to their abundant end groups, biocompatibility, and nontoxic degradation products. However, their practical application is hampered by tedious synthesis procedures. The present work described a novel organo-catalyzed “A1+B2“-ring-opening polymerization (ROP) using a monofunctional primary alc. (A1) as an initiator and a bicyclic carbonate monomer (B2) for the straightforward synthesis of HBPCs under mild conditions. No gelation was observed up to 90% conversion of the cyclic carbonate ring. HBPCs with molar masses in the range from 7 to 20 kg/mol were obtained. Based on the “A1+B2“-ROP, HBPCs bearing a variety of functionalities including alkene, alkyne, aldehyde, furan, azide, and mPEG groups, which are of great significance in the field of click chem., have been successfully prepared by using functional alc. initiators. This polymerization strategy allowed for precise control over the HBPC structure: (1) the hyperbranched polymer (HBP) backbone can be adjusted by design of a bicyclic carbonate monomer with various linkages; (2) the use of an appropriate initiator leads to the introduction of functional end groups. Overall, the “A1+B2“-ROP provides an efficient method for preparing a variety of HBPs like hyperbranched polyester, polyether, polyphosphate, and poly(amino acid) with complex architectures in a single step. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Synthetic Route of C13H10O3).
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Synthetic Route of C13H10O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics