The pyrolysis of tobacco ingredients was written by Baker, Richard R.;Bishop, Louise J.. And the article was included in Journal of Analytical and Applied Pyrolysis in 2004.Quality Control of Ethyl 3-ethoxypropanoate The following contents are mentioned in the article:
Relationships between tobacco components and smoke products are complex and often difficult to unravel. Pyrolysis experiments have commonly been used to establish such relationships. However, unless they are performed under dynamic conditions that are relevant to those that occur during tobacco burning, results can be obtained which have little resemblance to those obtained during cigarette smoking. The relevance of pyrolysis experiments to the behavior of tobacco ingredients in a burning cigarette is considered. Based on the temperature, heating rate, oxygen levels and gas flow conditions that occur inside the burning zone of a cigarette, together with a review of relevant pyrolysis and smoking experiments, a set of pyrolysis conditions has been developed that approximates those occurring in the pyrolysis region of the burning cigarette. The conditions include heating the sample at 30掳 s-1 from 300 to 900掳 under a flow of 9% oxygen in nitrogen. Experiments on the pyrolytic behavior of eleven relatively volatile substances under these conditions give results that are in good agreement with results from thirteen published studies in which cigarettes incorporating labeled versions of the substances were smoked. Subsequently, 291 single-compound tobacco ingredients have been pyrolyzed under this set of conditions, most of which are relatively volatile. This enables the behavior of these ingredients in a burning cigarette to be estimated in terms of intact transfer to mainstream smoke vs. pyrolytic decomposition It is predicted that almost a third of the substances would transfer to mainstream smoke at least 99% intact, and almost two-thirds would transfer 95% intact. Where pyrolytic decomposition does occur, the products are listed together with an estimate of the levels in smoke that would arise from the ingredient. This study involved multiple reactions and reactants, such as Ethyl 3-ethoxypropanoate (cas: 763-69-9Quality Control of Ethyl 3-ethoxypropanoate).
Ethyl 3-ethoxypropanoate (cas: 763-69-9) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters contain a carbonyl center, which gives rise to 120掳 C鈥揅鈥揙 and O鈥揅鈥揙 angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C鈥揙鈥揅 bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Quality Control of Ethyl 3-ethoxypropanoate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics