Ojovan, Michael I. et al. published their research in Molecules in 2020 |CAS: 118-55-8

The Article related to glass forming organic liquid viscous flow, activation energy, glass transition temperature, glass-forming liquids, viscosity, viscous flow, General Physical Chemistry: General Theories and other aspects.Synthetic Route of 118-55-8

Ojovan, Michael I. published an article in 2020, the title of the article was On viscous flow in glass-forming organic liquids.Synthetic Route of 118-55-8 And the article contains the following content:

The two-exponential Sheffield equation of viscosity η (T) = A1·T·[1 + A2·exp(Hm/RT)]·[1 + C·exp(Hd/RT)], where A1, A2, Hm, C, and Hm are material-specific constants, is used to analyze the viscous flows of two glass-forming organic materials-salol and α-phenyl-o-cresol. It is demonstrated that the viscosity equation can be simplified to a four-parameter version: η(T) = [A·T·exp(Hm/RT)]·[1 + C·exp(Hd/RT)]. The Sheffield model gives a correct description of viscosity, with two exact Arrhenius-type asymptotes below and above the glass transition temperature, whereas near the Tg it gives practically the same results as well-known and widely used viscosity equations. It is revealed that the constants of the Sheffield equation are not universal for all temperature ranges and may need to be updated for very high temperatures, where changes occur in melt properties leading to modifications of A and Hm for both salol and α-phenyl-o-cresol. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Synthetic Route of 118-55-8

The Article related to glass forming organic liquid viscous flow, activation energy, glass transition temperature, glass-forming liquids, viscosity, viscous flow, General Physical Chemistry: General Theories and other aspects.Synthetic Route of 118-55-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics