On August 14, 2013, Li, Tao; Kozlowski, Mark T.; Doud, Evan A.; Blakely, Maike N.; Rosi, Nathaniel L. published an article.Recommanded Product: 1312703-30-2 The title of the article was Stepwise ligand exchange for preparation of family of mesoporous MOFs. And the article contained the following:
A stepwise ligand exchange strategy is utilized to prepare a series of isoreticular bio-MOF-100 analogs. Specifically, in situ ligand exchange with progressively longer dicarboxylate linkers is performed on single crystalline starting materials to synthesize products with progressively larger mesoporous cavities. The new members of this series of materials, bio-MOFs 101-103, each exhibit permanent mesoporosity and pore sizes ranging from ∼2.1-2.9 nm and surface areas ranging from 2704 to 4410 m2/g. The pore volume for bio-MOF 101 is 2.83 cc/g. Bio-MOF-102 and 103 have pore volumes of 4.36 and 4.13 cc/g, resp. Collectively, these data establish this unique family of MOFs as one of the most porous reported to date. The experimental process involved the reaction of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate(cas: 1312703-30-2).Recommanded Product: 1312703-30-2
The Article related to ligand exchange mesoporous metal organic framework dicarboxylate linker, Surface Chemistry and Colloids: Liquid-Gas Systems and other aspects.Recommanded Product: 1312703-30-2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics