On July 31, 2022, Li, Huai-Ming; Li, Guan-Dong; Li, Jun-Yu; Zhang, Teng published an article.SDS of cas: 1312703-30-2 The title of the article was An Iodine-Functionalized Metal-Organic framework for catalytic alkene bromination. And the article contained the following:
An iodine-functionalized metal-organic framework (MOF), UiO-68-I, was synthesized. UiO-68-I showed good catalytic activity for dibromination of alkenes and alkynes with a low catalyst loading of 1% and was able to be recycled and recovered efficiently. Mechanistic studies suggest that UiO-68-I may trigger the formation of mol. bromine through a radical intermediate and thus accelerate the reaction. The activity and stability of UiO-68-I outperforms most earlier reports on organoiodine catalysts, showing the great potential of iodine-functionalized MOFs as recyclable heterogeneous hypervalent iodine reagents or catalysts. The experimental process involved the reaction of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate(cas: 1312703-30-2).SDS of cas: 1312703-30-2
The Article related to zirconium iodoterphenyldicarboxylate uio 68 mof preparation bromination catalyst, Inorganic Chemicals and Reactions: Coordination Compounds and other aspects.SDS of cas: 1312703-30-2
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