Volkov, G. U.; Rudnaya, G. V.; Berent, N. I. published an article in 1988, the title of the article was Crosslinking and degradative transformations in a film during oxidation.Category: esters-buliding-blocks And the article contains the following content:
Oxidative crosslinking of model coatings from piperylene rubber SKP-N and dodecyl methacrylate (I) or butyrate proceeded via formation of O-containing groups; the degradation of SKP-N prevailed and no significant polymerization of I was observed Low d.p. of I was attributed to degradative chain transfer from alkyl and, especially, peroxide radicals of I on SKP-N with formation of stable allyl radicals. The crosslinking of coatings from SKP-N and neopentyl glycol dimethacrylate (II) was oxidative in the top layer and was due to homopolymerization of II in the bottom (adjacent to substrate) layer when coatings contained a small amount of II. The homopolymer of II was insignificantly in thin coatings, owing to degradative chain transfer, but increased in the coatings with thickness 60-70 μ. Increasing the content of II ≥65% resulted in oxidative crosslinking throughout the film, apparently because of the increased O diffusion. The experimental process involved the reaction of 2,2-Dimethylpropane-1,3-diyl bis(2-methylacrylate)(cas: 1985-51-9).Category: esters-buliding-blocks
The Article related to crosslinking piperylene rubber methacrylate coating, oxidation piperylene rubber methacrylate coating, degradation piperylene rubber methacrylate coating, Coatings, Inks, and Related Products: Curing Processes and Agents and other aspects.Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics