On January 5, 2008, Fedorov, Andrei V.; Ermoshkin, Andrey A.; Neckers, Douglas C. published an article.Reference of 2,2-Dimethylpropane-1,3-diyl bis(2-methylacrylate) The title of the article was Remote polymerization of coatings with the release of borane from its amine complex. And the article contained the following:
We define remote polymerization as the formation of a photopolymer without the benefit of either light or a photoinitiator. In the reported experiments, a radical-generating trialkylborane-oxygen system was used with an active trialkylborane that was released from its stable amine complex by a vaporous (i.e., gas-phase) reagent. Acrylates and methacrylates were polymerized after oxidative radical formation from the highly reactive borane. The experimental process involved the reaction of 2,2-Dimethylpropane-1,3-diyl bis(2-methylacrylate)(cas: 1985-51-9).Reference of 2,2-Dimethylpropane-1,3-diyl bis(2-methylacrylate)
The Article related to remote radical polymerization coating borane release amine complex, Chemistry of Synthetic High Polymers: Organic Addition Polymerization and other aspects.Reference of 2,2-Dimethylpropane-1,3-diyl bis(2-methylacrylate)
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