On December 28, 2020, Yu, Bao; Perfetto, Anna; Allievi, Luca; Dhambri, Sabrina; Rager, Marie-Noelle; Selkti, Mohamed; Ciofini, Ilaria; Lannou, Marie-Isabelle; Sorin, Geoffroy published an article.Computed Properties of 10472-24-9 The title of the article was Silver(I) Oxide-/DBU-Promoted Synthesis of Dihydrofuran Units through Allenyl Silver Formation. And the article contained the following:
Herein, a formal [3+2] cyclization mediated by silver(I) oxide and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) was described. Through a broad variety of carbonyl compounds, this system can promote cyclization reactions with high yield (up to 85%) and diastereoselectivity (up to 95:5) for a straightforward access to complex and congested dihydrofuran derivatives in one step under mild conditions. Based on DFT studies, the proposed mechanism would involve an allenyl silver intermediate. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Computed Properties of 10472-24-9
The Article related to polycyclic dihydrofuran preparation, keto ester silver catalyst diastereoselective heterocyclization, allenyl silver, dihydrofuran, intramolecular cyclization, isomerization and other aspects.Computed Properties of 10472-24-9
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