On September 26, 2022, Wang, Songlin; Jiang, Nan; Peng, Jiali; Yang, Peng; Cui, Chengxing; Niu, Hongying; Zhang, Qiying; Wang, Jianji published an article.Reference of Phenyl Salicylate The title of the article was Efficient Synthesis of Diphenyl Carbonate from CO2, Phenol, and Carbon Tetrachloride under Mild Conditions. And the article contained the following:
Herein, an efficient catalytic system for the direct synthesis of DPC from CO2, phenol, and carbon tetrachloride was developed by using a ZnCl2/copper triflate (Cu(OTf)2) composite catalyst. For the first time, high yield and high selectivity were achieved for DPC synthesis under mild conditions, even at atm. pressure. Carefully designed control experiments and DFT studies indicated that the synergistic activation of Cu(OTf)2 and its anion complex with ZnCl2 for phenol and CO2 led to a remarkably improved catalytic activity through a Lewis acid-assisted catalysis. This study not only provides a new strategy for efficient preparation of DPC but also offers an effective pathway for better CO2 utilization. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Reference of Phenyl Salicylate
The Article related to phenol carbon dioxide zinc chloride copper triflate carbonylation, diphenyl carbonate preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.Reference of Phenyl Salicylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics