Qiao, Chang; Yao, Xiang-Yang; Liu, Xiao-Fang; Li, Hong-Ru; He, Liang-Nian published an article in 2018, the title of the article was Efficient Iron-Catalyzed Reductive N-Alkylation of Aromatic Amines with Carboxylic Acids and Phenylsilane.Application of 85-91-6 And the article contains the following content:
Herein, an earth-abundant iron-catalyzed protocol for the N-alkylation of anilines using carboxylic acid as alkyl source and phenylsilane as reducing agent was reported. With Fe2(CO)9 as a catalyst, a broad range of primary and secondary anilines are successfully converted to the corresponding tertiary anilines. Furthermore, this N-alkylation mainly goes through the amide pathway; while the aldehyde pathway can not be ruled out. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Application of 85-91-6
The Article related to tertiary aniline preparation green chem, aniline carboxylic acid reductive alkylation iron catalyst phenylsilane, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Application of 85-91-6
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